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Explanation:

Evaporation occurs when a liquid substance changes into a gas by heating the water. The first particles to evaporate from a liquid are those with the highest kinetic energy. The aggregate amount of this kinetic energy transfer is named as thermal energy which occurs only when there is a differential in the water molecule's temperature. Liquid water that becomes water vapor takes a parcel of heat with it in a process called evaporative cooling.

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Answer:

particles with the highest kinetic energy

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