The compound B2O3 is molecular.
A molecular compound consists of molecules whose formula represents the actual number of atoms bonded together in the molecule. The atoms are joined to give a definite shape which is defined by the angles between the bonds and by the bond lengths.
An ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding. The compound is neutral overall.
In the compound B2O3, the two boron atoms are bonded together and held by the three oxygen atoms at its sides. The basic unit of the structure consists of oxygen atoms arranged in planar chains of equilateral triangles and containing a centered boron atom. Therefore for its definite shape and definite bond length, angle it is considered as molecular.
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